过氧化氢
过硫酸盐
萘普生
化学
氨基三乙酸
EDDS公司
柠檬酸
乙二胺四乙酸
乙二胺
草酸盐
蒸馏水
配体(生物化学)
流出物
核化学
螯合作用
催化作用
无机化学
环境化学
有机化学
色谱法
环境工程
替代医学
重金属
受体
病理
工程类
医学
植物修复
生物化学
作者
Gizele D. Silva,Eduardo O. Marson,Letícia Leandro Batista,Carlos Ueira-Vieira,Maria Clara V.M. Starling,Alam G. Trovó
标识
DOI:10.1016/j.psep.2021.01.005
摘要
This is the first study to compare the combination of different iron complexes (Fe3+-oxalate (FeOx), Fe3+-citrate (FeCit), Fe3+-nitrilotriacetic acid (FeNTA), Fe3+-ethylenediaminetetraacetic acid (FeEDTA) and Fe3+-ethylenediamine-N,N′-disuccinic acid (FeEDDS) with distinct oxidants (H2O2 and S2O82−) on the degradation of naproxen (NAP) via photo-Fenton. Experiments were performed in distilled water and in sewage treatment plant effluent and different Fe/organic ligand molar ratios, oxidant concentrations and radiation sources (black light and sunlight) were tested for each complex. Photo-Fenton at neutral pH was efficient for naproxen degradation in the presence of all iron complexes. Fe/ligand molar ratio was strongly affected by the ligand type, best results were obtained in the presence of Fe/EDDS (1:1) and Fe/NTA (1:1), Fe/EDTA (1:2), Fe/Cit (1:3) and Fe/Ox (1:12). Although NAP removal in distilled water was faster in the presence of H2O2 (max 20 kJ m−2 required) when compared to S2O82− (max 90 kJ m−2 required), better performance of S2O82− was observed in sewage treatment plant effluent. Antimicrobial activity was only observed in the presence of FeEDDS, yet it was eliminated after treatment in the presence of S2O82−. A critical comparison in terms of operational and electrical energy costs indicates that using FeCit complex with H2O2 is the most cost-effective alternative in both matrices.
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