丁酸
化学
发酵
甲烷
拉曼光谱
拉曼散射
密度泛函理论
滴定法
醋酸
挥发性脂肪酸
气相色谱法
脂肪酸
色谱法
分析化学(期刊)
有机化学
计算化学
物理
光学
瘤胃
作者
Raju Botta,Pongpan Chindaudon,Pitak Eiamchai,Mati Horprathum,Saksorn Limwichean,Chanunthorn Chananonnawathorn,Viyapol Patthanasettakul,Apichai Jomphoak,Raju Botta
摘要
Abstract Volatile fatty acids of acetic, butyric, lactic, and propionic acids play an important role in the methane fermentation process. Particularly significant amount of propionic acid presence in the process will influence the methane fermentation efficiency. Herein, zigzag‐aligned silver nanorods were designed as surface‐enhanced Raman scattering (SERS)‐active substrates to establish the classification of volatile fatty acids against the traditional poor sensitive and time‐consuming titration and gas chromatography methods. SERS and chemometric method of principal component analysis is used for the detection and classification of volatile fatty acids. Density functional theory calculations were performed to understand the Raman vibrations and compare with experimental observations and to aid in the assignments of spectral lines. For the first time, the authors have used SERS technique to classify the acids. The findings suggest that this method is of great potential in the field of methane fermentation from industrial waste.
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