化学
分子间力
羧酸盐
催化作用
药物化学
高分子化学
立体化学
有机化学
分子
作者
Yutaka Tanji,Ryo Hamaguchi,Yasushi Tsuji,Tetsuaki Fujihara
摘要
A bulky carboxylic acid bearing one 1-adamantylmethyl and two methyl substituents at the α-position is demonstrated to work as an efficient carboxylate ligand source in Pd-catalyzed intermolecular C(sp2)-H bond arylation reactions. The reactions proceeded smoothly under mild conditions, taking advantage of the steric bulk of the carboxylate ligands.
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