结块
煤
化学工程
碳纤维
硫黄
催化作用
材料科学
反应性(心理学)
流化床
流态化
化学
废物管理
有机化学
复合材料
复合数
病理
替代医学
工程类
医学
作者
Shuai Yan,Xuanhui Qu,Zihong Xia,Caixia Chen,Jing Bi
出处
期刊:Fuel
[Elsevier]
日期:2021-07-01
卷期号:296: 120652-120652
被引量:10
标识
DOI:10.1016/j.fuel.2021.120652
摘要
Coal catalytic hydrogasification is an efficient approach to produce CH4. This study investigated hydrogasification characteristic of coal with diverse properties (caking propensity, high rank and sulfur content) in a pressurized fluidized bed. The approaches to realize high CH4 yield and stable fluidization were explored. Experimental results showed that carbon structure and sulfur content in coal were the key factors influencing hydrogasification reactivity. The mechanically mixed CaO/CaCO3 migrated into the interior of coal particle to enhance the activity of Co towards graphite carbon, and capture sulfur adsorbing on Co surface. The caking propensity of coal brought little resistance to the activity of catalyst, whereas, caused serious agglomerating phenomenon. The blending of caking coal with non-caking, low rank coals induced the active hydrogen spill-over and the volatiles-catalyst-coal interactions, which not only in-situ minimized the agglomeration propensity, but also enhanced the overall hydrogasification reactivity. Furthermore, the mechanism of hydrogasification was proposed by taking account of coal property, to broadening the application range of hydrogasification and producing CH4 efficiently (~80.0 wt% in 1.0 h).
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