背光
材料科学
半最大全宽
光致发光
色域
液晶显示器
成核
蓝宝石
光电子学
复合数
纳米复合材料
荧光粉
复合材料
光学
作者
Yixuan Lu,Yawen Xu,Shuxin Chen,Jidong Lin,Jiwen Zhu,Shaoxiong Wang,Yuanhui Zheng,Feng Huang,Daqin Chen
标识
DOI:10.1016/j.jlumin.2022.118952
摘要
Perovskite quantum dots are considered an ideal alternative to traditional phosphor color converters because of their excellent optical properties. However, the bottleneck problem of instability has tremendously limited their practical applications. In the present work, we fabricate green-emitting CsPbBr 3 @glass and red-emitting CsPbBr 1.5 I 1.5 @glass nanocomposites via an in-situ nucleation/growth method. Importantly, the CsPbX 3 @glass (X 3 = Br 3 , Br 1.5 I 1.5 ) samples exhibit striking thermal reversibility in the heating/cooling cycle experiments. Furthermore, CsPbX 3 monolithic films with high photoluminescence quantum yields (PLQYs) of 80–95% and narrow full-width at half-maximum (FWHM) down to 16 nm are achieved by dispersing ground CsPbX 3 @glass particles in polydimethylsiloxane (PDMS) matrix. Benefiting from dual encapsulation of inorganic glass matrix and organic polymer matrix, the film can endure harsh accelerated aging tests (at 85 °C/85%RH for 500 h). Finally, combining the as-prepared yellow monolithic film with blue chips as the backlight endows the liquid crystal display (LCD) with a wide color gamut (a color gamut of 146% of commercial LCD, 101% of NTSC after passing the color filters), demonstrating great prospects in the display industry. • CsPbX 3 (X 3 = Br 3 , Br 1.5 I 1.5 ) QDs were in-situ precipitated inside glass matrix via controlling nucleation/growth process. • CsPbX 3 monolithic films exhibited high PLQY of 80–95% and FWHM down to 16 nm. • The CsPbX 3 @glass@PDMS composite films possessed extremely excellent moisture and heat resistance. • A white LED backlit unit was simply achieved by coupling a yellow composite film with blue chips. • The color gamut of screen reached 101% NTSC 1953 standard and 146% commercial LCD after passing the color filters.
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