铀酰
膦酸盐
铀
材料科学
吸附
水溶液
荧光
结晶度
热液循环
化学工程
多孔性
无机化学
核化学
有机化学
化学
冶金
复合材料
物理
量子力学
工程类
作者
Hongxia Zhao,Chao Qi,Xuewu Yan,Jinyan Ji,Zhifang Chai,Shuao Wang,Tao Zheng
标识
DOI:10.1021/acsami.2c01671
摘要
The material for managing and monitoring waste made from the waste itself is an excellent example of cyclic utilization, which could reduce issues and be more sustainable. A three-dimensional porous uranyl phosphonate MOF (UPF-105) was synthesized via a hydrothermal method. UPF-105 is stable in aqueous solution with pH in the range of 1-11 and maintains crystallinity below 215 °C. The uncoordinated phosphonate groups in the channels act as functional anchors to selectively capture uranyl ions, with a maximum uranium adsorption capacity of 170.23 mg g-1. The fluorescence of UPF-105 makes it a good candidate for a uranyl ion sensor in uranium-contaminated solutions with concentrations in the range of 5-90 ppm.
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