Polymerizable Deep Eutectic Solvent‐Based Skin‐Like Elastomers with Dynamic Schemochrome and Self‐Healing Ability

Animal skin is a huge source of inspiration when it comes to multifunctional sensing materials. Bioinspired sensors integrated with the intriguing performance of skin-like steady wide-range strain detection, real-time dynamic visual cues, and self-healing ability hold great promise for next-generation electronic skin materials. Here, inspired by the skins of a chameleon, cellulose nanocrystals (CNCs) liquid crystal skeleton is embedded into polymerizable deep eutectic solvent (PDES) via in situ polymerization to develop a skin-like elastomer. Benefiting from the elastic ionic conductive PDES matrix and dynamic interfacial hydrogen bonding, this strategy has broken through the limitations that CNCs-based cholesteric structure is fragile and its helical pitch is non-adjustable, endowing the resulting elastomer with strain-induced wide-range (0-500%) dynamic structural colors and excellent self-healing ability (78.9-90.7%). Furthermore, the resulting materials exhibit high stretch-ability (1163.7%), strain-sensing and self-adhesive abilities, which make them well-suitable for developing widely applicable and highly reliable flexible sensors. The proposed approach of constructing biomimetic skin-like materials with wide-range dynamic schemochrome is expected to extend new possibilities in diverse applications including anti-counterfeit labels, soft foldable displays, and wearable optical devices.