An overview of the deactivation mechanism and modification methods of the SCR catalysts for denitration from marine engine exhaust

Selective catalytic reduction (SCR) technology is currently the most effective deNOx technology and has broad application prospects. Moreover, there is a large NOx content in marine engine exhaust. However, the marine engine SCR catalyst will be affected by heavy metals, SO2, H2O(g), hydrocarbons (HC) and particulate matter (PM) in the exhaust, which will hinder the removal of NOx via SCR. Furthermore, due to the high loading operation of the marine engine and the regeneration of the diesel particulate filter (DPF), the exhaust temperature of the engine may exceed 600 °C, which leads to sintering of the SCR catalysts. Therefore, the development of new catalysts with good tolerances to the above emissions and process parameters is of great significance for further reducing NOx from marine engines. In this work, we first elaborate on the mechanism of the SCR catalyst poisoning caused by marine engine emissions, as well as the working mechanism of SCR catalysts affected by the engine exhaust temperature. Second, we also summarize the current technologies for improving the properties of SCR catalysts with the aim of enhancing the resistance and stability under complex working conditions. Finally, the challenges and perspectives associated with the performance optimization and technology popularization of marine SCR systems are discussed and proposed further. Consequently, this review may provide a valuable reference and inspiration for the development of catalysts and improvement in the denitration ability of SCR systems matched with marine engines.