Soluble Porous Coordination Polymers by Mechanochemistry: From Metal‐Containing Films/Membranes to Active Catalysts for Aerobic Oxidation

Soluble porous coordination polymers from mechanochemical synthesis are presented through a coordination polymerization between highly contorted, rigid tetraphenol and a broad variety of transition metal ions. These polymers can be easily cast as metal-containing films or freestanding membranes. Importantly, as-made coordination polymers are highly active and stable in the aerobic oxidation of allylic C-H bonds.