Tough Ionogels: Synthesis, Toughening Mechanisms, and Mechanical Properties─A Perspective

Polymeric ionogels are polymer networks swollen with ionic liquids (i.e., salts with low melting points). Ionogels are interesting due to their unique features such as nonvolatility, high thermal and electrochemical stability, excellent ionic conductivity, and nonflammability. These properties enable applications such as unconventional electronics, energy storage devices (i.e., batteries and supercapacitors), sensors and actuators. However, the poor mechanical performance of ionogels (e.g., fracture strength < 1 MPa, modulus < 0.1 MPa, and toughness < 1000 J m-2) have limited their use, thus motivating the need for tough ionogels. This Perspective summarizes recent advances toward tough ionogels by highlighting synthetic methods and toughening mechanisms. Opportunities and promising applications of tough ionogels are also discussed.