Radiation synthesis of covalently/non-covalently coupled all ionic liquid-based Ionogels with rapid self-healing, environmental tolerance for multifunctional ionic skin

As novel artificial ion-conducting materials with skin-like functionalities, Ionic skins (I-Skins) have attracted wide attention in the field of smart wearables. Nonetheless, the crucial hurdle of maintaining their properties in extreme conditions, such as cold, hot or long-term storage, persists. Herein, ionic liquid monomers, ionic liquid solvents, and ionic liquid cross-linkers are employed to facilitate covalently/non-covalently coupled all ionic liquid-based Ionogel for multimodal artificial I-skin through electron beam irradiation under mild conditions at the first time. Profiting from the covalently/non-covalently interactions in the Ionogel, the Ionogel has tunable mechanical properties, excellent environmental adaptability (−60 to 150 °C), long-term stability (90 days), fast response time (0.1 s), rapid self-healing ability (120 s recovery to 90 % of original), and favorable adhesion properties. Moreover, Ionogel sensors possess the remarkable capability to accurately perceive external stimuli, including strain, temperature, and humidity, similar to human skin, which can effectively monitor human movement behavior, as well as fluctuations in ambient temperature and humidity. It is expected that this all ionic liquid-based Ionogel sensor can fill the gap of I-Skin in extreme conditions and realize multifunctional flexible sensing, thus expanding more application scenarios.