3D g-C3N4 porous nanoribbons pillared-MXene/ PVA nanocomposite: An architecture with high dielectric, breakdown strength, thermal conductivity, and mechanical strength characteristics

In polymer nanocomposites with conductive fillers, obtaining boosted dielectric constant, breakdown strength, lower dielectric loss concurrently, and mixing to build a homogeneous structure is challenging. In this work, 3D g-C3N4 porous nanoribbons pillared-MXene/PVA nanocomposite (MXene/CNNR/PVA) was fabricated. The solution casting method was utilized for embedding Mxene/CNNR into poly (vinyl alcohol) (PVA) to produce MXene/CNNR/PVA dielectric composites. The maximum observed electrical displacement is 10.95 μC/cm2 at (T = 25 °C and E = 400 MV/m). Furthermore, the obtained density of discharged energy is 18.11 J/cm3, much higher than that of pristine PVA (4.21 J/cm3 at E = 200 MV/m). The relative permittivity of 3.5 wt% ternary composites (MXene/CNNR/PVA) at 25 °C and 1000 Hz is 25.1, and the loss is just 0.03. Moreover, the combined use of MXene and CNNR results in a synergistic effect; the MXene/CNNR/PVA composite films exhibit more incredible mechanical characteristics compared to pure PVA nanocomposite modified by MXene alone, with notable increases in tensile strength and Young’s modulus while retaining the majority of its elasticity.