纳米针
材料科学
介孔材料
扫描电子显微镜
介电谱
拉曼光谱
锂(药物)
阳极
X射线光电子能谱
化学工程
透射电子显微镜
高分辨率透射电子显微镜
电化学
分析化学(期刊)
纳米技术
电极
纳米结构
复合材料
化学
色谱法
内分泌学
光学
催化作用
医学
生物化学
物理
工程类
物理化学
作者
Zhenyu Huang,Yongfeng Yuan,Zhijie Lin,Jingkai Lin,S.B. Li,S.Y. Guo,Yuanhe Huang,Weiwei Yan
标识
DOI:10.1016/j.jallcom.2023.172458
摘要
Fluffy ultrathin WO3 nanoneedle clusters are in-situ grown in mesoporous hollow carbon nanospheres (MHCSs) via unique material impregnation and confined molten reaction in MHCS nanoreactors. Through transmission electron microscopy, scanning electron microscopy, X-ray diffraction, Raman spectra and X-ray photoelectron spectroscopy analyses, it can be found that WO3 nanoneedles with 5~10 nm in thickness and ~140 nm in length are encapsulated within each MHCS with 150~250 nm in diameter and 30~40 nm in shell thick. Thermal gravimetric analysis reveals the WO3 content of 83.5 wt%. Lithium storage performance was evaluated by galvanostatic charge/discharge cycling, cyclic voltammogram and electrochemical impedance spectroscopy. The composite exhibits remarkable rate performance (average discharge capacity of 1352 mAh g−1 at 0.1 A g−1 and 105 mAh g−1 at 10 A g−1) and excellent cycling performance (1094 mAh g−1 at 0.2 A g−1 after 50 cycles, 760 mAh g−1 at 1 A g−1 after 500 cycles, 351 mAh g−1 at 5 A g−1 after 2000 cycles). The composite also presents outstanding kinetics properties, such as high Li+ diffusion coefficient, strong capacitive effect, and low electrochemical impedance. The superior electrochemical performance is attributed to unique “ship-in-a-bottle” structure. MHCSs facilitate electron transfer and ion diffusion, buffer volume change of WO3 and maintain the integrity of WO3. Furthermore, fluffy ultrathin nanoneedle cluster structure endows WO3 with high electrochemical activity.
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