矫顽力
材料科学
晶间腐蚀
微观结构
相(物质)
合金
相图
磁铁
凝聚态物理
熔点
冶金
分析化学(期刊)
复合材料
化学
物理
有机化学
量子力学
色谱法
作者
P. Tozman,H. Sepehri-Amin,Taichi Abe,K. Hono,Y. K. Takahashi
标识
DOI:10.1016/j.actamat.2023.119197
摘要
Magnetic isolation of hard magnetic grains with an intergranular phase is a key factor in obtaining high coercivity, which has been established in the microstructure of Nd-Fe-B magnets owing to the phase equilibrium of hard magnetic Nd2Fe14B with a low melting point phase. In this work, we investigated the phase equilibrium in the Sm-Fe-V system to establish an optimum composition range to develop high coercivity SmFe12-based permanent magnets. In addition to the solid 1:12/liquid Sm-rich phase equilibrium, an additional V-rich phase is found for the first time in the Sm-Fe-V phase diagram for V contents between 19 to 35 at.% at 1500 K. The equilibrium between the 1:12 phase and the two phases with low melting points is computationally modeled for Sm-Fe-V metastable phase diagram. This is experimentally confirmed by analyzing the microstructure of the Sm8Fe72V20 thin film, where anisotropic columnar 1:12 grains are enveloped with predominantly V-rich phases along with some Sm-rich intergranular phases resulting in a coercivity (µ0Hc) of 0.9 T. Although this large V content in Sm(Fe,V)12-based alloy is not beneficial for achieving a large magnetization, the finding of a new V-rich intergranular phase can benefit the development of anisotropic sintered magnets via two alloy powder methods; one alloy powder with large V-content for forming intergranular phase and the other with V-lean content to maintain a large magnetizations. To further improve the coercivity to its highest limit μ0Hc ≈0.2-0.3Ha ≈2-3 T, decreasing the ferromagnetic elements in the intergranular phase is essential.
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