Abstract Further investigation of the isoflavonoids in white lupin roots has revealed a new coumaronochromone with a 2-hydroxy-3-methyl-3-butenyl side chain (lupinalbin G), three new pyrano-isoflavones (lupinisoflavones K and L, and allolicoisoflavone B) and two new di-hydrofurano-isoflavones each with a 2,3-dihydroxy-3-methylbutyl substituent (lupinisoflavones M and N). The biogenetic pathways for these and other lupin isoflavones are briefly discussed.