镧系元素
发光
检出限
猝灭(荧光)
金属有机骨架
选择性
化学
水溶液中的金属离子
金属
离子
分析化学(期刊)
无机化学
荧光
材料科学
物理化学
光电子学
色谱法
有机化学
催化作用
物理
量子力学
吸附
作者
Kexin Wang,Zhenglin Han,Xiaokun Wen,Xiaoxuan Fan,Feifei Yin,Baijie Guan,Hong Xia,Jiwei Wang,Liu Wen,Tianya Tan
标识
DOI:10.1016/j.microc.2023.109668
摘要
The development of probes for the detection of multiple heavy metal ions holds the nonnegligible practical significance for ensuring public and environment safety. In this work, a ratiometric luminescence probe was proposed for the detection Cu2+ and Fe3+ based lanthanide metal–organic framework@polyethyleneimine (Ln-MOF@PEI). The formation of the complexes between PEI and Cu2+ enhances the quenching efficiency of MOF through a combination of inner filter effect and energy transfer, surpassing the observed quenching efficiency with Fe3+. The emission intensity ratio between Tb3+ and the ligands exhibits a decreasing trend with increasing Cu2+ concentration, while it rises with increasing Fe3+ concentration. It allows for the discrimination between Cu2+ and Fe3+ based on their distinct quenching mechanisms. The assay performance of Ln-MOF@PEI probes was evaluated comprehensively. The limit of detection for Cu2+ and Fe3+ reaches at 9.7 nM and 37.4 nM, respectively. The probe demonstrates acceptable selectivity by effectively avoiding interference from common cations and anions. The detection range covers a wide concentration range from nanomoles to millimoles. Overall, the luminescence probe is expected to meet the requirements of accurate quantification for Cu2+ and Fe3+ in the various application scenarios.
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