Fast and Sensitive Detection of CO by Bi-MOF-Derived Porous In2O3/Fe2O3 Core–Shell Nanotubes

In₂O₃ is an optimal material for sensitive detection of carbon monoxide (CO) gas due to its low resistivity and high catalytic activity. Yet, the gas response dynamics between the CO gas molecules and the surface of In₂O₃ is limited by its solid structure, resulting in a weak gas response value and sluggish electron transport. Herein, we report a strategy to synthesize porous In₂O₃/Fe₂O₃ core-shell nanotubes derived from In/Fe bimetallic organic frameworks. The fabricated porous In₂O₃/Fe₂O₃-4 core-shell nanotubes present outstanding gas sensitivities, including a response value 3.8 times (33.7 to 200 ppm CO at 260 °C) higher than that of monometallic-derived In₂O₃ (8.7), ultrashort response and recovery times (23/76 s) to 200 ppm CO, low detection limit (1 ppm), promising selectivity, and long-term stability. The enhanced sensing mechanisms are clarified by the combination of experiment and first-principles calculations, showing that the synergetic strategy of higher adsorption energy, increased electrical conductivity, higher electron transfer numbers, and larger specific surface area of porous core-shell structures promotes the surface activity and charge transfer efficiency. The present work paves a way to tune gas-sensing materials with special morphologies for the development of high-performance CO sensors.