Personal Perspective on Strain-Induced Polymer Crystallization

Semicrystalline polymer materials are commonly strong yet tough after processed through fiber spinning, film stretching (or blowing), and plastic molding (or foaming), which are fundamentally related with strain-induced crystallization. This paper provides a personal perspective on thermodynamics and kinetics aspects of strain-induced polymer crystallization, mainly based on the author's recent research experience. The thermodynamic studies include homopolymers, random copolymers, solution polymers, and blend polymers. The kinetic studies cover three sequential crystallization stages, i.e., crystal nucleation, crystal growth, and postgrowth. The thermodynamic driving forces join with the kinetic barriers to determine the crystal nucleation mechanisms and the structure evolution at the molecular level, which yield unique polymer crystal morphologies from lamellar crystals to shish-kebab crystals and eventually fibril crystals. The resulting semicrystalline structures were discussed with their implications for the mechanical properties of products. Some future studies were briefly proposed.