二亚胺
苝
铜
锡
阴极
电极
材料科学
钙钛矿(结构)
光电子学
化学
冶金
分子
有机化学
物理化学
作者
Jorim Okoth Obila,Du Hyeon Ryu,Sangsuk Oh,Jun Hyung Kim,Robinson Musembi,Seungjin Lee,Bong Joo Kang,Nam Joong Jeon,Elijah Ayieta,Sang Hyuk Im,Chang Eun Song
出处
期刊:ACS energy letters
[American Chemical Society]
日期:2024-02-20
卷期号:: 1090-1096
标识
DOI:10.1021/acsenergylett.3c02795
摘要
Interfacial modulation is crucial for optimizing charge carrier management and thwarting undesired ion-metal diffusion in perovskite photovoltaics. This study highlights a groundbreaking approach, employing semiconducting perylene-diimide (PDINN) as a cathode interlayer (CIL) in an inverted tin halide perovskite solar cell (THPSC). PDINN imparts the THPSCs with a remarkable efficiency rate of 13.05% as well as substantial stability, achieving the best performance among reported THPSCs thus far. The incorporation of PDINN improves the energy level alignment and mitigates the interfacial trap density, with PDINN also serving as a robust diffusion barrier to Cu and I ions due to the strong interactions between it and the PC61BM electron transport layer or the Cu cathode. The PDINN CIL introduced in this study is a pioneering application in THPSCs that concurrently boosts efficiency while also ensuring unprecedented stability.
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