化学
水溶液
荧光
镉
聚合物
配体(生物化学)
水溶液中的金属离子
土霉素
组合化学
配位聚合物
环丙沙星
离子
抗生素
有机化学
生物化学
物理
受体
量子力学
作者
Xiangqian Li,Peiying Yang,Yuxin Zhao,Yang Li,Mingru Li,Xinyu Wang,Ji Wu,Jian Shen,Xinlei Wang,Hongyan He,Zhe Lin,Xuliang Zhang,Shuang Ma
出处
期刊:Polyhedron
[Elsevier]
日期:2024-03-01
卷期号:250: 116818-116818
标识
DOI:10.1016/j.poly.2023.116818
摘要
Over the past two decades, large amounts of antibiotics have been discharged into the aquatic environment, threatening human health and ecological balance. Meanwhile, numerous reports have documented coordination polymers as a fluorescent sensing material for detecting pollutants in aqueous environments. We successfully synthesized a two-dimensional coordination polymer using Cd2+ ions and the rigid ligand 1-(3,4-dicarboxyphenyl)-4-hydroxypyridin (H2L) and named it [Cd(L)]n (1). In this complex, each cadmium ion exhibits a six-coordinated pattern and forms a two-dimensional network structure with a (6,3)Ia-type topology according to the ToposPro software. In addition, the good stability and excellent fluorescence properties of the complex made it an excellent fluorescent sensor for the identification of ciprofloxacin and oxytetracycline in aqueous solution with low limits of detection (0.28 μM for ciprofloxacin and 36.5 μM for oxytetracycline). Finally, we investigated the detailed mechanism of the fluorescence sensing behavior of the complex by performing density functional theory calculations.
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