Prediction of petroleum viscosity from molecular weight and density

粘度 原油 热力学 油粘度 绝对偏差 化学 经验模型 分析化学(期刊) 数学 色谱法 统计 石油工程 物理 计算机科学 工程类 程序设计语言
作者
Dicho Stratiev,Ivelina Shishkova,Rosen Dinkov,Svetoslav Nenov,Sotir Sotirov,Evdokia Sotirova,Iliyan Kolev,Vitaly Ivanov,Simeon Ribagin,Krassimir Atanassov,Danail D. Stratiev,Dobromir Yordanov,Dimitar Nedanovski
出处
期刊:Fuel [Elsevier BV]
卷期号:331: 125679-125679 被引量:17
标识
DOI:10.1016/j.fuel.2022.125679
摘要

165 crude oils with viscosity, density, and molecular weight variation in the range 0.54 – 24135cP; 0.746 – 1.016 g/cm3; 117–579 g/mol respectively were examined for viscosity prediction using eight available in the literature models and three more, developed in this work models. The best empirical model was that of Sinha et al., 2020 with % AAD (absolute average deviation) = 18.2 %, The ANN (artificial neural network) model for the data set of the 165 crude oils outperformed the empirical correlations with % AAD = 17.7 %. 93 crude oils with viscosity, density, molecular weight, and SARA composition data variation in the range 2.3 – 23 000cP; 0.819 – 0.992 g/cm3; 179–579 g/mol; Sat.: 26.0–79.3 %; Aro:11.9–52.8 %; Res.: 2.5–30.9; Asp.:0.1–19.6 % respectively were also examined for viscosity prediction by the available in the literature empirical correlations and another new developed empirical correlation that includes besides molecular weight and density, the crude oil saturate content. The best empirical model was that developed in this work with saturate content inclusion, that showed % AAD = 23.8 %. The ANN model for the data set of 93 crude oils again outperformed the empirical correlations with % AAD = 18.8 %. The most accurate model predicting viscosity was found the new developed in this work model on the base of a reference viscosity at a particular temperature and molecular weight with %AAD = 2.5 %.

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