过电位
制氢
电解水
催化作用
分解水
材料科学
化学工程
电化学
氢
电催化剂
电解
镍
碱性水电解
氢氧化钾
纳米棒
纳米技术
化学
冶金
电极
光催化
物理化学
有机化学
工程类
电解质
作者
Sen Hu,Cuili Xiang,Yongjin Zou,Fen Xu,Lixian Sun
出处
期刊:Nanomaterials
[MDPI AG]
日期:2023-06-16
卷期号:13 (12): 1871-1871
被引量:4
摘要
As traditional energy structures transition to new sources, hydrogen is receiving significant research attention owing to its potential as a clean energy source. The most significant problem with electrochemical hydrogen evolution is the need for highly efficient catalysts to drive the overpotential required to generate hydrogen gas by electrolyzing water. Experiments have shown that the addition of appropriate materials can reduce the energy required for hydrogen production by electrolysis of water and enable it to play a greater catalytic role in these evolution reactions. Therefore, more complex material compositions are required to obtain these high-performance materials. This study investigates the preparation of hydrogen production catalysts for cathodes. First, rod-like NiMoO4/NiMo is grown on NF (Nickel Foam) using a hydrothermal method. This is used as a core framework, and it provides a higher specific surface area and electron transfer channels. Next, spherical NiS is generated on the NF/NiMo4/NiMo, thus ultimately achieving efficient electrochemical hydrogen evolution. The NF/NiMo4/NiMo@NiS material exhibits a remarkably low overpotential of only 36 mV for the hydrogen evolution reaction (HER) at a current density of 10 mA·cm-2 in a potassium hydroxide solution, indicating its potential use in energy-related applications for HER processes.
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