Adsorption of Rhodamine B and Pb(II) from aqueous solution by MoS2 nanosheet modified biochar: Fabrication, performance, and mechanisms

Mediated by polydopamine, MoS2 nanosheets were immobilized on the porous biochar derived from fungus residue, forming a novel biochar-based nanocomposite (MoS2-PDA@FRC) for the removal of Rhodamine B(RhB) and Pb(II) from water. Utilizing MoS2 nanosheets with abundant active adsorption sites, MoS2-PDA@FRC showed higher adsorption capacities than raw biochar, with 2.76 and 1.78 times higher capacities for RhB and Pb(II) respectively. MoS2-PDA@FRC also exhibited fast adsorption kinetics for RhB (120 min) and Pb (180 min) removal, as well as satisfactory adsorption selectivity in the presence of coexisting substances. The underlying removal mechanism was explored via Fourier transform infrared and X-ray photoelectron spectroscopies. Furthermore, during cyclic adsorption-regeneration and the fixed-bed adsorption experiments, the nanocomposite removed RhB and Pb(II) with high effectiveness and stability. Collectively, the results demonstrated the bright prospects of MoS2-PDA@FRC as a highly efficient decontamination agent of RhB and Pb(II) from water.