胺气处理
化学
盐酸盐
盐(化学)
溶解度
乙腈
惰性气体
药物化学
色谱法
有机化学
标识
DOI:10.1002/047084289x.rn01312
摘要
[91-00-9] C13H13N (MW 183.25) InChI = 1S/C13H13N/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13H,14H2 InChIKey = MGHPNCMVUAKAIE-UHFFFAOYSA-N [5267-34-5] C13H14NCl (MW 219.71) InChI = 1S/C13H13N.ClH/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12;/h1-10,13H,14H2;1H InChIKey = CIHWJRSPVJBHGT-UHFFFAOYSA-N (serves as a stable protected amine with several methods of deprotection; can be incorporated in chiral catalysts or used in the substrate for a variety of asymmetric addition reactions) Alternate Names: benzhydrylamine, diphenylmethyl amine (DPM-amine, DPM-NH2); aminodiphenylmethane; benzhydrylamine hydrochloride. Physical Data: for [91-00-9]: bp 295 °C (flash point 113 °C), mp 12 °C, d = 1.063 g mL−1 @ 25 °C; for [5267-34-5]: mp 293–295 °C. Solubility: soluble in most organic solvents; the HCl salt is soluble in water. Form Supplied in: for [91-00-9] : colorless liquid; for [5267-34-5] : white crystalline powder; both are commercially available. Preparative Methods: phenyl Grignard addition to phenyl acetonitrile;1 exposure to HCl to form the HCl salt.7 Handling, Storage, and Precautions: harmful if inhaled or swallowed and can be irritating to the eyes, skin, and respiratory system; should be stored under an inert gas due to the hygroscopic nature; distill the amine before use.
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