膜
纳滤
Zeta电位
流动电流
表面电荷
化学工程
阳离子聚合
分子
巴(单位)
多孔性
化学
材料科学
膜技术
表面改性
分析化学(期刊)
色谱法
纳米技术
高分子化学
复合材料
有机化学
物理化学
纳米颗粒
气象学
工程类
物理
生物化学
作者
Shu Xu,Dongwei Lu,Panpan Wang,Yumeng Zhao,Yan Sun,Jingyao Qi,Jun Ma
标识
DOI:10.1016/j.memsci.2020.117885
摘要
A dual-charged composite membrane was engineered for efficient separation of both cationic and anionic molecules. Alternately charged functional layer with sandwich structure was assembled onto porous membrane via chemical-mediated polyphenol surface engineering. The surface morphology, element variation and surface charge properties of the functional layer were respectively analysed using SEM, FTIR and streaming zeta potential measurements. The as-prepared “sandwich”-type composite membrane showed preferable rejection to multiple charged dyes (99.6% Alcian blue, 99.3% Brilliant blue, 92.21% Methyl blue, 89.91% Rhodanile blue). Both Donnan repulsion by dual-charged functional layer and entrapment effect by micro electric fields contributed to the outstanding separation performance. Compared with generally needed high pressure of 4–8 bar for the current nanofiltration separation, the developed composite membrane achieved desirable rejection under a low operating pressure of 1.5 bar, as well as favorable recycling performance for long-term use. This study provides an energy-efficient membrane candidate for comprehensive separation of charged molecules in practical applications such as dye wastewater treatment.
科研通智能强力驱动
Strongly Powered by AbleSci AI