Chemical Synthesis of Magnetic Nanoparticles for Permanent Magnet Applications

Abstract Permanent magnets are a class of critical materials for information storage, energy storage, and other magneto‐electronic applications. Compared with conventional bulk magnets, magnetic nanoparticles (MNPs) show unique size‐dependent magnetic properties, which make it possible to control and optimize their magnetic performance for specific applications. The synthesis of MNPs has been intensively explored in recent years. Among different methods developed thus far, chemical synthesis based on solution‐phase reactions has attracted much attention owing to its potential to achieve the desired size, morphology, structure, and magnetic controls. This Minireview focuses on the recent chemical syntheses of strongly ferromagnetic MNPs ( H c >10 kOe) of rare‐earth metals and FePt intermetallic alloys. It further discusses the potential of enhancing the magnetic performance of MNP composites by assembly of hard and soft MNPs into exchange‐coupled nanocomposites. High‐performance nanocomposites are key to fabricating super‐strong permanent magnets for magnetic, electronic, and energy applications.