光异构化
化学
二芳基乙烯
部分
焓
熵(时间箭头)
立体化学
热力学
光致变色
光化学
有机化学
异构化
催化作用
物理
作者
Alexander V. Strizhak,Oleg Babii,Sergii Afonin,Iuliia Bakanovich,Teodors Pantelejevs,Wenshu Xu,Elaine Fowler,Rohan S. Eapen,Krishna Sharma,М. О. Платонов,Vasyl Hurmach,Laura S. Itzhaki,Marko Hyvönen,Anne S. Ulrich,David R. Spring,Igor V. Komarov
摘要
Photoisomerization of diarylethene-modified peptides changes the thermodynamics of their binding to MDM2: the “closed” photoisomers bind largely due to a high negative enthalpy, whereas the “open” forms bind better due to a more favourable entropy.
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