材料科学
电化学
二硫化钼
催化作用
电催化剂
拉曼光谱
X射线光电子能谱
循环伏安法
化学工程
析氧
电解质
无机化学
电极
阳极
冶金
物理化学
生物化学
光学
物理
工程类
化学
作者
Yunqie Deng,Zhen Liu,Aizhu Wang,Sun D,Yuke Chen,Linjing Yang,Jinbo Pang,Hai Li,Haidong Li,Hong Liu,Weijia Zhou
出处
期刊:Nano Energy
[Elsevier]
日期:2019-08-01
卷期号:62: 338-347
被引量:102
标识
DOI:10.1016/j.nanoen.2019.05.036
摘要
Molybdenum disulphide (MoS2) presents a promising electrocatalyst for hydrogen evolution reaction (HER). Immense effort has been made to optimize MoS2 catalysts with more active sites for the sake of satisfying HER performance. In this work, the MoS2 is modulated by electrochemical anodic activation at positive potentials in acidic media to fast intercalate oxygen into MoS2 in 200 s, leading to the dramatic enhancement for HER activity. Cyclic voltammetry, high-resolution transmission electron microscopy, X-ray photoelectron spectroscopy, in situ atomic force microscope and operando Raman spectroscopy are applied to explore the oxygen doping process of MoS2 in 0.5 M H2SO4 electrolyte. In brief, the optimal oxygen doped MoS2 catalyst exhibits an onset potential of as low as −87 mV vs. RHE at 1 mA cm−2 accompanied by excellent stability, which is reduced about 50 mV compared to that before electrochemical anodic activation of MoS2 (135 mV). This work will create a simple and universal method to improve the activities of catalysts by electrochemical anodic activation process, which was successfully applied to MoS2, MoSe2 and MoP.
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