材料科学
三元运算
复合数
光催化
石墨烯
异质结
纳米结构
可见光谱
辐照
化学工程
产量(工程)
纳米技术
催化作用
化学
光电子学
复合材料
物理
有机化学
工程类
程序设计语言
核物理学
计算机科学
作者
Abdullah Bafaqeer,Muhammad Nawaz Tahir,Azmat Ali Khan,Nor Aishah Saidina Amin
标识
DOI:10.1021/acs.iecr.8b06053
摘要
Indirect Z-scheme assembly of graphene-bridged 2D ZnV2O6/pCN nanosheets composite has been fabricated by one-step solvothermal process and tested for photoinduced CO2 conversion under visible-light irradiations. The highest CH3OH production of 3488 μmol g-cat–1 was obtained over ZnV2O6/RGO/g-C3N4 composite, 1.02 and 1.25 times higher comparing to ZnV2O6/RGO and ZnV2O6/g-C3N4 samples, respectively. This enhanced efficiency can be ascribed to well-designed ternary heterojunction with hierarchical structure and efficient charges separation by RGO. More importantly, CH3OH yield was further improved by introducing RGO/pCN as an electron sink, which led to a 1.07 times higher yield than using only RGO. This reveals that ternary 2D ZnV2O6/RGO/pCN nanostructure has higher visible-light absorption, improved charge separation, and enhanced photocatalytic efficiency due to RGO/pCN as multiple mediators. The stability of composite catalyst also prevailed for 32 h for continuous CH3OH production. Therefore, structured Z-scheme composite with multiple electron mediators enables efficient CO2 conversion under visible-light irradiation.
科研通智能强力驱动
Strongly Powered by AbleSci AI