化学
氰基乙酸乙酯
阳极
催化作用
活性炭
联轴节(管道)
无机化学
药物化学
有机化学
电极
物理化学
机械工程
丙二腈
工程类
吸附
作者
R. Shundo,Ikuzo Nishiguchi,Yoshiharu Matsubara,Tsuneaki Hirashima
出处
期刊:Chemistry Letters
[The Chemical Society of Japan]
日期:1990-12-01
卷期号:19 (12): 2285-2288
被引量:13
摘要
Novel carbon-carbon bond formation of non-activated olefins with ethyl cyanoacetate has been developed by anodic oxidation using only a small amount of Mn(OAc)2·4H2O to give selectively either saturated or unsaturated coupling products depending upon the presence of a catalytic amount of Cu(OAc)2·H2O.
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