酰亚胺
锂(药物)
电化学
电解质
无机化学
化学
碳酸乙烯酯
盐(化学)
离子液体
循环伏安法
材料科学
电导率
有机化学
高分子化学
电极
催化作用
物理化学
医学
内分泌学
作者
Hongjing Han,Sisi Zhou,Daijun Zhang,Shouhua Feng,Lifei Li,Kai Li,Wenfang Feng,Jun Nie,Hong Li,Xuejie Huang,Michel Armand,Zhibin Zhou
标识
DOI:10.1016/j.jpowsour.2010.12.040
摘要
Lithium bis(fluorosulfonyl)imide (LiFSI) has been studied as conducting salt for lithium-ion batteries, in terms of the physicochemical and electrochemical properties of the neat LiFSI salt and its nonaqueous liquid electrolytes. Our pure LiFSI salt shows a melting point at 145 °C, and is thermally stable up to 200 °C. It exhibits far superior stability towards hydrolysis than LiPF6. Among the various lithium salts studied at the concentration of 1.0 M (= mol dm−3) in a mixture of ethylene carbonate (EC)/ethyl methyl carbonate (EMC) (3:7, v/v), LiFSI shows the highest conductivity in the order of LiFSI > LiPF6 > Li[N(SO2CF3)2] (LiTFSI) > LiClO4 > LiBF4. The stability of Al in the high potential region (3.0–5.0 V vs. Li+/Li) has been confirmed for high purity LiFSI-based electrolytes using cyclic voltammetry, SEM morphology, and chronoamperometry, whereas Al corrosion indeed occurs in the LiFSI-based electrolytes tainted with trace amounts of LiCl (50 ppm). With high purity, LiFSI outperforms LiPF6 in both Li/LiCoO2 and graphite/LiCoO2 cells.
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