Visible-light-promoted defluorinative ring-opening gem-difluoroallylation of cycloalkanols using 1-trifluoromethyl alkenes

A photocatalytic redox-neutral defluorinative ring-opening coupling of cycloalkanols with α-trifluoromethyl alkenes for the synthesis of gem -difluoroalkenes bearing a distal carbonyl group was developed.