光电流
材料科学
可见光谱
光致发光
光催化
表面等离子共振
等离子体子
纳米颗粒
吸收光谱法
吸收(声学)
化学气相沉积
图层(电子)
光电子学
纳米技术
光化学
化学工程
化学
催化作用
光学
复合材料
有机化学
工程类
物理
作者
Zhiguang Sun,Chenyang Liu,Xiao‐Song Li,Yurui Fang,Xiaobing Zhu,Ai‐Min Zhu
标识
DOI:10.1016/j.matchemphys.2022.125773
摘要
Conventionally supported nanoparticle (NP) of plasmonic Au/TiO2 performs well under visible light, however the problem with cost, activity and durability inevitably remains. Here we demonstrate a semi-transparent nanofilm of plasmonic Au/TiO2 by deposition-precipitation and atmospheric chemical vapor deposition methods. Onto a synthetic TiO2 nanofilm (bottom layer), Au NP is allocated (top layer) for direct exposure to light with enhanced utilization efficiency (low cost). Compared to the conventional coating film from NPs, its growth nanofilm formed from molecular assembly is considered more durable. Effects of localized surface plasmon resonance (LSPR) and Fabry-Pérot (F–P) interference are evidenced by UV–vis absorption spectra. To identify and further utilize separation efficiency of charge carriers, photoluminescence spectra and visible-light photocurrent experiment in a three-electrode electrochemical cell were conducted. Using formaldehyde oxidation as reaction model, visible-light photocatalysis over plasmonic Au/TiO2 nanofilm is conceptually verified. The presence and size of Au NP promotes light absorption, separation of charge carriers and photocurrent. Au/TiO2 exhibits up to 10 times photocurrent at applied potential compared to TiO2. Inspiringly, over Au/TiO2 nanofilm, apparent rate constant, kapp (ca. 0.49 s−1) is unprecedentedly achieved ca. 3-4 orders of magnitude larger than TiO2-based thin films reported in literatures. Our growth nanofilm of Au/TiO2, achieves reaction rate of 5.0 × 10−7 mol s−1·gcat−1 under green LED that is even higher than the conventional supported NP, which is of significance to be considered more durable with the improved interface. Consequently, our semi-transparent nanofilm of plasmonic Au/TiO2 addresses cost, activity and durability for visible-light photocatalysis, for which it may pave a way to large-scale application from a practical perspective.
科研通智能强力驱动
Strongly Powered by AbleSci AI