燃烧
稻草
热重分析
吉布斯自由能
活化能
焓
污水污泥
化学
动力学
化学工程
催化作用
热力学
材料科学
环境工程
无机化学
污水
物理化学
有机化学
环境科学
工程类
物理
量子力学
作者
Chengxin Wang,Xinhua Wang,Xuedan Jiang,Fengyu Li,Yanyan Lei,Qizhao Lin
标识
DOI:10.1016/j.fuproc.2019.02.024
摘要
This study investigated the combustion characteristics and kinetics of sewage sludge (SS), wheat straw (WS) and their blends using thermogravimetric analysis, under air condition. Combustion characteristic parameters of SS blended with 5%–50% WS was enhanced, especially revealed by an increase in comprehensive combustion index. A significant synergetic interaction was found in high temperature region through experiments. When proportion of WS was 50%, the synergetic interaction was strongest. And the catalytic effect of alkali metal oxides in WS ash on the combustion of SS residues at high temperature region had a strong effect on synergetic interaction. Metal oxides circulated in different oxide forms to transport oxygen to carbon surface, leading to catalytic effect. Activation energy was evaluated by two isoconversional method: Flynn-Wall-Ozawa and Vyazovkin method. The lowest average activation energies of the blends were obtained at 50% wheat straw blending ratio (89.29 kJ/mol by FWO and 87.48 kJ/mol by V, respectively). The thermodynamic parameters (Gibbs free energy, Entropy and Enthalpy) were also obtained. And two master plots methods were utilized to determine the appropriate fit kinetic model of combustion which can be described by Avarami-Erofeve (A2).
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