Design of a Recyclable Photoresponsive Adsorbent via Green Synthesis of Ag Nanoparticles in Porous Aromatic Frameworks for Low-Energy Desulfurization

= 1, 2, 3), were thoroughly characterized to confirm successful synthesis and structural integrity. The introduced Ag NPs serve as adsorption sites, enhancing uptake capacity through weak interactions with sulfur atoms in thiophenic molecules. More significantly, under light irradiation, the localized surface plasmon resonance (LSPR) of Ag NPs enables efficient photothermal conversion, triggering rapid desorption without conventional heating. Adsorption-desorption tests demonstrated that up to 48% of adsorbed thiophenic sulfur could be released upon illumination. Fixed-bed experiments further verified that light can effectively stimulate regeneration and improve energy efficiency. This work offers a promising strategy for designing recyclable adsorbents with low-energy regeneration driven by clean solar energy.