Photoinduced Synthesis of γ-Amino Alcohols via [2,3]-Acyloxy Migration

An efficient photoinduced strategy for the synthesis of γ -amino alcohols via intramolecular [2,3]-acyloxy migration is described. This transformation enables the direct synthesis of γ -amino alcohols, valuable intermediates in organic synthesis, through N -centered radical addition, intramolecular acyloxy migration, and subsequent nucleophilic attack.