钝化
材料科学
串联
钙钛矿(结构)
光伏
带隙
光电子学
硒化铜铟镓太阳电池
卤化物
光伏系统
纳米技术
太阳能电池
化学工程
无机化学
图层(电子)
复合材料
化学
电气工程
工程类
作者
Tianyi Huang,Rui Wang,Selbi Nuryyeva,Shaun Tan,Jingjing Xue,Yepin Zhao,Quantan Wu,Marc H. Weber,Pei Cheng,Dong Meng,İlhan Yavuz,K. N. Houk,Yang Yang
出处
期刊:Small
[Wiley]
日期:2021-12-06
卷期号:18 (8)
被引量:2
标识
DOI:10.1002/smll.202103887
摘要
Superior bandgap tunability enables solution-processed halide perovskite a promising candidate for multi-junction photovoltaics (PVs). Particularly, optically coupling wide-gap perovskite by stacking with commercially available PVs such as silicon and CIGS (also known as 4-terminal tandem) simplifies the technology transfer process, and further advances the commercialization potential of perovskite technology. However, compared with matured PV materials and the phase-pure FAPbI3 , wide-gap perovskite still suffers from huge voltage deficits. Here, the authors take advantage of the synergetic effect behind a sequential fluoride and organic ammonium salt surface passivation strategy to control non-radiative energy losses, and obtained a 17.7% efficiency in infrared-transparent wide-gap perovskite solar cells (21.1% for opaque device), and achieved efficiencies of over 25% when stacked with commercial Si and CIGS products with original PCEs of 18-20% under a 4-terminal working condition.
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