废止
立体中心
配体(生物化学)
催化作用
吡唑酮类
组合化学
化学
立体化学
对映选择合成
有机化学
受体
生物化学
作者
Youbin Peng,Xiaohong Huo,Wanbin Zhang
出处
期刊:Chem catalysis
[Elsevier]
日期:2023-07-01
卷期号:3 (7): 100673-100673
标识
DOI:10.1016/j.checat.2023.100673
摘要
In this issue of Chem Catalysis, Huang and co-workers report a Pd-catalyzed stereodivergent [4 + 2] annulation of alkylidene pyrazolones with vinyl benzoxazinanones via ligand regulation, synthesizing an array of [6.5]-spiropyrazolones bearing three contiguous stereocenters with high yields and stereoselectivities. The origin of this stereodivergent annulation process was revealed by DFT calculation.
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