材料科学
薄膜
金属有机骨架
单层
化学气相沉积
多孔性
纳米技术
钛
沉积(地质)
化学工程
同种类的
图层(电子)
有机化学
化学
冶金
复合材料
吸附
热力学
古生物学
物理
沉积物
工程类
生物
作者
María Romero‐Ángel,Víctor Rubio‐Giménez,Eloy P Gómez-Oliveira,M Verstreken,Jorid Smets,Jesús Gándara-Loe,Natalia M. Padial,Rob Ameloot,Sergio Tatay,Carlos Martí‐Gastaldo
标识
DOI:10.1021/acs.chemmater.3c01389
摘要
Heterobimetallic Metal–Organic Frameworks (MOFs) synergically combine the properties of two metal ions, thus offering significant advantages over homometallic MOFs in gas storage, separation, and catalysis, among other applications. However, these remain centered on bulk materials, while applications that require functional coatings on solid supports are not developed. We explore for the first time the deposition of heterometallic Ti-based MOF thin films using vapor-assisted conversion on substrates functionalized with a self-assembled monolayer. Furthermore, metal-induced dynamic topological transformation allows the conversion of MUV-10(Ca) films into MUV-101(Co) and MUV-102(Cu), which is not accessible through direct synthesis, without morphologically altering the films. These nonconventional thin-film deposition techniques enable homogeneous and crystalline coatings of heterometallic titanium MOFs that also maintain their corresponding porosity.
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