煅烧
热重分析
催化作用
碳化作用
化学工程
流化床
混流
烧结
等温过程
化学
材料科学
冶金
有机化学
地质学
热力学
工程类
物理
岩土工程
地下水
作者
Iwei Wang,Siyi Huang,Shihui Wang,Xuan Bie,Hui Zhou,Zhenshan Li
标识
DOI:10.1016/j.seppur.2023.125975
摘要
This study explores the performance of dual-functional materials (DFMs) in cyclic integrated CO2 capture and reverse water–gas shift (ICCU-RWGS) reactions under fluidized, isothermal conditions. DFMs with a copper catalyst and alumina support on calcined natural limestone were analyzed using micro-fluidized bed thermogravimetric analysis coupled with mass spectrometry (MFB-TGA-MS). The results indicate that the 10 %Cu5%Al-CaO-IMP surpasses others, demonstrating a CO2 capture capacity of 10.67 mmol⋅g−1, 71.5 % in-situ CO2 conversion at 700 °C, and remarkable cyclic stability over 30 cycles. Cu and Al additions curtail CaO agglomeration during extended ICCU-RWGS and enhance CO2 and H2 activation by removing surface formate species, promoting CO production. Furthermore, non-catalytic gas–solid reactions coexist with catalytic gas–solid reactions, leading to gradual Cu particle coating by CaCO3 during carbonation. This phenomenon prevents Cu sintering but slightly reduces catalytic activity. These findings, combined with cost-effective materials (CaO, Cu, Al), hold significant promise for efficient and economically viable ICCU processes.
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