As the demand for high-performance hydrophones for marine communication systems grows, this paper develops a high-frequency unfilled layered symmetrical piezoelectric material with high effective electromechanical coupling coefficient. The kt vibration mode of piezoelectric material is converted into k33 vibration mode of the piezoelectric pillar to improve the effective electromechanical coupling coefficient of the material. The material is determined by the equivalent circuit method and ANSYS finite element simulation method. Test results show that the resonant frequency is 117.8 kHz and the effective electromechanical coupling coefficient is 0.67, which shows that the developed material has a good electromechanical conversion performance.