For $\mathbb B^n$ the unit ball of $\mathbb C^n$, we consider Bergman-Orlicz spaces of holomorphic functions in $L^Φ_α$, which are generalizations of classical Bergman spaces. We characterize the dual space of large Bergman-Orlicz space, and bounded Hankel operators between some Bergman-Orlicz spaces $A_α^{Φ_1}(\mathbb B^n)$ and $A_α^{Φ_2}(\mathbb B^n)$ where $Φ_1$ and $Φ_2$ are either convex or concave growth functions.