聚酰亚胺
材料科学
剥脱关节
共价有机骨架
荧光
共价键
热稳定性
透射电子显微镜
卟啉
化学工程
聚合物
光化学
检出限
多孔性
纳米技术
石墨烯
有机化学
复合材料
化学
光学
色谱法
物理
工程类
图层(电子)
作者
Cuiling Zhang,Shiming Zhang,Yinghan Yan,Fei Xia,Anni Huang
标识
DOI:10.1021/acsami.6b16423
摘要
A new fluorescent polyimide covalent organic framework (PI-COF) has been successfully synthesized through solvothermal route using tetra(4-aminophenyl) porphyrin and perylenetracarboxylic dianhydride, which possesses porous crystalline and excellent thermal stability (>500 °C). Furthermore, few-layered PI covalent organic nanosheets (PI-CONs) can be easily obtained from the fluorescent PI-COF through a facile liquid phase exfoliation approach, which were confirmed by atomic force microscopy and transmission electron microscopy analysis. It is interesting that the fluorescent intensity of PI-CONs is obviously enhanced relative to that of PI-COF. The PI-CONs have been successfully utilized as an efficient fluorescent probe for the highly sensitive and selective detection of 2,4,6-trinitrophenol (TNP). The mechanism might be attributed to the combination of electron transfer and inner filter effect based on DFT calculations and spectral overlap data. The system exhibits a good linear response toward TNP over the range from 0.5 to 10 μM with a detection limit of 0.25 μM.
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