电催化剂
过电位
分解水
双功能
析氧
镍
催化作用
无机化学
化学
拉曼光谱
材料科学
化学工程
电化学
物理化学
电极
冶金
有机化学
物理
光催化
光学
工程类
作者
Fang Luo,Shuyuan Pan,Yuhua Xie,Chen Li,Yanke Yu,Zehui Yang
标识
DOI:10.1016/j.jechem.2023.10.007
摘要
Urea oxidation reaction (UOR) has been selected as substitution for oxygen evolution reaction ascribing to its low thermodynamic voltage as well as utilization of nickel as electrocatalyst. Herein, we report the formation of nickel single atoms (Ni-SAs) as exceptional bifunctional electrocatalyst toward UOR and hydrogen evolution reaction (HER) in urea-assisted water splitting. In UOR catalysis, Ni-SAs perform a superior catalytic performance than Ni-NP/NC and Pt/C ascribing to the formation of HOO-Ni-N4 structure evidenced by in-situ Raman spectroscopy, corresponding to a boosted mass activity by 175-fold at 1.4 V vs. RHE than Ni-NP/NC. Furthermore, Ni-SAs requires only 450 mV overpotential to obtain HER current density of 500 mA cm−2. 136 mA cm−2 is achieved in urea-assisted water splitting at 1.7 V for Ni-SAs, boosted by 5.7 times than Pt/C-IrO2 driven water splitting.
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