离解(化学)
电解质
电化学
电催化剂
催化作用
化学
分子
吸附
Boosting(机器学习)
分解水
水的自电离
析氧
电极
无机化学
化学工程
化学物理
材料科学
物理化学
计算机科学
有机化学
光催化
机器学习
工程类
标识
DOI:10.1002/anie.202307303
摘要
In the past, the design of efficient electrocatalyst materials for alkaline hydrogen evolution reaction (HER) was mostly focused on tuning the adsorption properties of reaction intermediates. A recent breakthrough shows that the performance can be improved by manipulating water structure at the electrode-electrolyte interface using atomically localized electric fields. The new approach was realized by using IrRu dizygotic single-atom sites and led to a significantly accelerated water dissociation and an overall improved alkaline HER performance. Supported by extensive data from advanced modeling, characterization, and electrochemical measurements, the work delivers an intricate examination of the interaction between water molecules and the catalyst surface, thereby enriching our understanding of water dissociation kinetics and offering new insights to boost overall alkaline HER efficiency.
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