Hydroxypropyl Cellulose‐Based Meter‐Long Structurally Colored Fibers for Advanced Fabrics

Abstract Structurally colored fibers are attractive alternatives to chemically colored fibers due to their rich optical properties, color stability, and environmental friendliness. However, the fabrication of structurally colored fibers using cost‐effective raw materials with the possibility to scale up remains challenging. Here, a simple and scalable approach is developed to fabricate continuous meter‐long structurally colored fibers exhibiting brilliant structural colors across the visible spectrum and helix orientation‐dependent polarization states. The fibers are fabricated by extrusion of concentrated aqueous solutions of chemically crosslinked hydroxypropyl cellulose (HPC). The wavelengths and polarization states can be tuned by solution concentration, relaxation time, and collector's surface energy. The HPC‐based structurally colored fibers display excellent optical stability to mechanical straining, repeated drying/water impregnation, and prolonged heating at 150 °C. It is demonstrated that the HPC‐based structurally colored fibers can be woven into structurally colored fabrics with wavelength‐ and polarization‐coded optical patterns. The current work presents a strategy to tune the chiral nematic order, which constitutes an important step toward mass production of structurally colored fibers with stable and rich optical properties using easily available raw materials.