Multilevel Anti-counterfeiting Barcode with Enhanced Information Encryption Based on Stimulus-Responsive Digital Polymers

In response to the escalating challenges of counterfeiting due to technological and socioeconomic advancements, a novel trilevel anti-counterfeiting Quick Response (QR) code system has been developed. This system integrates digital polymers with QR code and stimulus-responsive chromophores, i.e., rhodamine B (RB), rhodamine 6G (R6G), and spiropyran (SP), to provide a sophisticated security solution. This advanced barcode remains concealed until specific stimuli reveal it and can be scanned by a smartphone, enabling first and second level anti-counterfeiting. For the third level of security, the encrypted information within the digital polymers can only be deciphered using tandem mass spectrometry. This innovative approach not only enhances security features but also offers reversible visibility and a complex verification process. This trilevel system surpasses traditional single-level anti-counterfeiting methods and holds significant potential for future applications in protecting brand authenticity and managing data storage, contributing new concepts and techniques to the field of high-security anti-counterfeiting materials.