铜
检出限
离子
微通道
二乙烯三胺
水溶液中的金属离子
无机化学
碳纤维
选择性
荧光
猝灭(荧光)
柠檬酸
化学
材料科学
分析化学(期刊)
纳米技术
色谱法
冶金
催化作用
光学
有机化学
复合材料
复合数
物理
作者
Yunfei Ma,Songtao Wang,Wei Sun,Longlong Zhou,Yiqing Deng,Qiang Zhao
摘要
ABSTRACT Copper ions (Cu 2+ ) play a crucial role in biological processes; however, excessive intake can result in severe health problems. Current methods for detecting copper ions are both expensive and complex. Therefore, there is a need for efficient and straightforward visual detection methods. In this study, novel nitrogen‐doped carbon dots (N‐CDs) were synthesized via a microchannel method using diethylenetriamine and citric acid as precursors and were characterized by TEM, XRD, and IR, among others. The N‐CDs demonstrated high selectivity and strong fluorescence, showing a linear quenching response to copper ions with a detection limit of 46 nM, whereas other common metal ions, such as Ca 2+ and Mg 2+ , exhibited negligible interference even at higher concentrations. These N‐CDs were subsequently applied to test paper, allowing for on‐site visual and quantitative detection of copper ions via a colorimetric method. This approach provides a novel solution for the rapid detection of copper ions, with significant potential in environmental monitoring, public health, and industrial applications.
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