MOF-based/derived catalysts for electrochemical overall water splitting

Water-splitting electrocatalysis has gained increasing attention as a promising strategy for developing renewable energy in recent years, but its high overpotential caused by the unfavorable thermodynamics has limited its widespread implementation. Therefore, there is an urgent need to design catalytic materials with outstanding activity and stability that can overcome the high overpotential and thus improve the electrocatalytic efficiency. Metal-organic frameworks (MOFs) based and/or derived materials are widely used as water-splitting catalysts because of their easily controlled structures, abundant heterointerfaces and increased specific surface area. Herein, some recent research findings on MOFs-based/derived materials are summarized and presented. First, the mechanism and evaluation parameters of electrochemical water splitting are described. Subsequently, advanced modulation strategies for designing MOFs-based/derived catalysts and their catalytic performance toward water splitting are summarized. In particular, the correlation between chemical composition/structural functionalization and catalytic performance is highlighted. Finally, the future outlook and challenges for MOFs materials are also addressed.