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PRODUCTION OF STYRENE BY DEHYDROGENATION OF ETHYLBENZENE

乙苯 脱氢 苯乙烯 化学 有机化学 催化作用 共聚物 聚合物
作者
Arzu Jalilova Samir Ganbarov Samir Ganbarov
出处
期刊:Proceedings of Azerbaijan High Technical Educational Institution [Aspendos International Academy of Medical and Social Sciences. LTD]
卷期号:53 (05): 461-470
标识
DOI:10.36962/pahtei53052025-461
摘要

In chemical manufacturing, styrene is a vital component that is frequently utilized as a major ingredient in raw materials, mostly for the production for polystyrene along with various polymers. Its commercial significance is important since it is essential to the manufacturing of plastics, copolymers, elastomers, and insulating materials. The presence of high temperatures, along with the application of certain catalysts, are necessary for the complex process of turning ethylbenzene into styrene. Improving this reaction becomes essential for reducing the consumption of energy and unwanted product production as well as for raising productivity within the industry. Typical catalysts have been linked to extreme temperatures and restrictions on the transfer of mass when utilized in the commercial synthesis of styrene from ethylbenzene. Fixed-bed granular converters frequently result in hot patches and unequal heat distribution inside the reactor, resulting in coke deposition and the production of byproducts. Coke production lowers the catalyst's performance and necessitates pe¬rio¬dic regeneration, adding to the operational and financial expenses. In the past few years, more ad¬van¬ced methods of manufacture, porous ceramic converters, and nanotechnology-based catalysts have been invented to address these problems. Compounds made from Al₂O₃-[Re,W]/γ-Al₂O₃ (K, Ce)/α are examples of contemporary catalytic structures that have porous architectures that enhance mass and heat transmission, which in turn improves reactivity efficiency Utilizing a unique porous cera¬mic Al₂O₃-[Re,W]/γ Al₂O₃(K, Ce)/α catalyst that was created via the sol-gel method and autonomous high-temperature reaction synthesis, the results of an investigation on the transformation of ethyl¬ben¬ze¬ne into styrene through the rremoval of hydrogen has been presented in this publication. The fin¬dings show this type of converter has virtually 100% selectivity for liquid products and a styrene yield that is around 23 times greater than that of traditional industrial converters. Furthermore, the carbon accumulation on the catalyst stays below 5 weight percent throughout 6 hours of reaction. To make an overview, Rhenium and Wolfram in the catalyst help expand the reaction kinetics factor, which means a more desirable reaction. The kalium promoter prevents the active side of the catalyst from blockage by reducing the rate of coke development. The role of Ce, here is to increase the re¬sis¬tance of the catalyst from aging and thermal deformation, and structure stabilization improves the lifecycle. Keywords: catalyst with ceramic porous, heterogeneous converter, rhenium-based catalysts, synthe¬sis of monomers, hydrogen removal on ethylbenzene, generation of styrene.

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